Inorg. Chem. 2022, 61, 19, 7560–7567. https://doi.org/10.1021/acs.inorgchem.2c00711

Organic–inorganic metal halides (OIMHs) exhibit excellent photoelectric properties; however, their high-temperature light-emission stability requires further improvement. Here, we report three isostructural OIMHs (C₂H₈N)₄InCl₇, (C₂H₈N)₄SbCl₇, and (C₂H₈N)₄SbBr₇ (C₂H₈N⁺ = dimethylammonium). They are all crystallized in the P2₁2₁2 space group with a zero-dimensional (0D) structure, with orange-red photoluminescence (PL) under 365 nm UV excitation. Among them, (C₂H₈N)₄InCl₇ exhibits the strongest PL with a photoluminescence quantum yield (PLQY) of 13.9% at room temperature. Optical property measurements and density functional theory unveil that the luminescence of (C₂H₈N)₄InCl₇ at 405 and 620 nm is due to free exciton and self-trapped exciton emission, respectively. It is worth noting that (C₂H₈N)₄InCl₇ shows a high PL quenching temperature, maintaining 50% of its room-temperature PL intensity at 425 K, which is rare in OIHMs. This is much higher than the application temperature of phosphors in practical solid-state lighting applications (363–383 K). In this temperature range, the luminous intensity of (C₂H₈N)₄InCl₇ exceeds 60% of that at room temperature. The high PL quenching temperature observed in (C₂H₈N)₄InCl₇ indicates the potential of OIMHs for applications in phosphor-converted light-emitting diodes.