Inorg. Chem. 2022, 61, 38, 15016–15022,https://doi.org/10.1021/acs.inorgchem.2c01900

Recently, excellent optical properties of low-dimensional organic–inorganic metal halides, stemming from their tunable structure and optoelectronic properties, have been demonstrated. The synthetic method is critical because it is highly related to the structure and properties of the halide. Herein, we obtain two different antimony bromides, (Bmpip)₂SbBr₅ and (Bmpip)₃Sb₂Br₉, which both possess the P2₁/c space group having different crystal structures, and this confirms the important influence of synthesis on the single-crystal structure. (Bmpip)₂SbBr₅ contains Bmpip⁺ and [SbBr₅]^2– pyramids, and (Bmpip)₃Sb₂Br₉ consists of Bmpip⁺ and Sb-based dimers [Sb₂Br₉]^3–. Under 400 nm excitation, (Bmpip)₂SbBr₅ exhibits a 640 nm orange emission with a quantum yield of ∼11.5% owing to Sb 5s² electron luminescence. A diode was fabricated by (Bmpip)₂SbBr₅ and commercial phosphors and showed a high color render index of 92. Our work reveals the effect of the preparation method on the crystal structure. A luminescent material was finally identified.