{"id":79,"date":"2021-03-09T15:03:21","date_gmt":"2021-03-09T07:03:21","guid":{"rendered":"http:\/\/www.ustb.cc\/?p=79"},"modified":"2025-10-28T09:14:50","modified_gmt":"2025-10-28T01:14:50","slug":"crystal-structure-and-y","status":"publish","type":"post","link":"http:\/\/ustb.cc\/zh\/crystal-structure-and-y\/","title":{"rendered":"Crystal structure and photoluminescence of (Y1\u2212xCex)2Si3O3N4"},"content":{"rendered":"\n<p><strong><em><mark style=\"background-color:rgba(0, 0, 0, 0)\" class=\"has-inline-color has-vivid-cyan-blue-color\">J. Lumin.<\/mark><\/em>, 2011, 131, 2, 336.<\/strong> <a rel=\"noreferrer noopener\" href=\"https:\/\/doi.org\/10.1016\/j.jlumin.2010.10.032\" target=\"_blank\">https:\/\/doi.org\/10.1016\/j.jlumin.2010.10.032<\/a><\/p>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-large\"><img decoding=\"async\" src=\"https:\/\/ars.els-cdn.com\/content\/image\/1-s2.0-S0022231310004643-gr4.jpg\" alt=\"\"\/><\/figure>\n<\/div>\n\n<address style=\"text-align: justify;\"><span style=\"color: #2e2e2e; font-family: NexusSerif, Georgia, 'Times New Roman', Times, STIXGeneral, 'Cambria Math', 'Lucida Sans Unicode', 'Microsoft Sans Serif', 'Segoe UI Symbol', 'Arial Unicode MS', serif; font-size: 18px; text-align: start;\">Oxonitridosilicate phosphors with compositions of (Y<span style=\"box-sizing: border-box; margin: 0px; padding: 0px; font-size: 13.5px; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em; color: #2e2e2e; font-family: NexusSerif, Georgia, 'Times New Roman', Times, STIXGeneral, 'Cambria Math', 'Lucida Sans Unicode', 'Microsoft Sans Serif', 'Segoe UI Symbol', 'Arial Unicode MS', serif;\">1\u2212<em style=\"box-sizing: border-box; margin: 0px; padding: 0px;\">x<\/em><\/span>Ce<span style=\"box-sizing: border-box; margin: 0px; padding: 0px; font-size: 13.5px; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em; color: #2e2e2e; font-family: NexusSerif, Georgia, 'Times New Roman', Times, STIXGeneral, 'Cambria Math', 'Lucida Sans Unicode', 'Microsoft Sans Serif', 'Segoe UI Symbol', 'Arial Unicode MS', serif;\"><em style=\"box-sizing: border-box; margin: 0px; padding: 0px;\">x<\/em><\/span>)<span style=\"box-sizing: border-box; margin: 0px; padding: 0px; font-size: 13.5px; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em; color: #2e2e2e; font-family: NexusSerif, Georgia, 'Times New Roman', Times, STIXGeneral, 'Cambria Math', 'Lucida Sans Unicode', 'Microsoft Sans Serif', 'Segoe UI Symbol', 'Arial Unicode MS', serif;\">2<\/span>Si<span style=\"box-sizing: border-box; margin: 0px; padding: 0px; font-size: 13.5px; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em; color: #2e2e2e; font-family: NexusSerif, Georgia, 'Times New Roman', Times, STIXGeneral, 'Cambria Math', 'Lucida Sans Unicode', 'Microsoft Sans Serif', 'Segoe UI Symbol', 'Arial Unicode MS', serif;\">3<\/span>O<span style=\"box-sizing: border-box; margin: 0px; padding: 0px; font-size: 13.5px; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em; color: #2e2e2e; font-family: NexusSerif, Georgia, 'Times New Roman', Times, STIXGeneral, 'Cambria Math', 'Lucida Sans Unicode', 'Microsoft Sans Serif', 'Segoe UI Symbol', 'Arial Unicode MS', serif;\">3<\/span>N<span style=\"box-sizing: border-box; margin: 0px; padding: 0px; font-size: 13.5px; line-height: 0; position: relative; vertical-align: baseline; bottom: -0.25em; color: #2e2e2e; font-family: NexusSerif, Georgia, 'Times New Roman', Times, STIXGeneral, 'Cambria Math', 'Lucida Sans Unicode', 'Microsoft Sans Serif', 'Segoe UI Symbol', 'Arial Unicode MS', serif;\">4<\/span>\u00a0(<em style=\"box-sizing: border-box; margin: 0px; padding: 0px; color: #2e2e2e; font-family: NexusSerif, Georgia, 'Times New Roman', Times, STIXGeneral, 'Cambria Math', 'Lucida Sans Unicode', 'Microsoft Sans Serif', 'Segoe UI Symbol', 'Arial Unicode MS', serif; font-size: 18px;\">x<\/em>=0\u22120.2) have been synthesized by solid state reaction method. The structures and photoluminescence properties have been investigated. Ce<span style=\"box-sizing: border-box; margin: 0px; padding: 0px; font-size: 13.5px; line-height: 0; position: relative; vertical-align: baseline; top: -0.5em; color: #2e2e2e; font-family: NexusSerif, Georgia, 'Times New Roman', Times, STIXGeneral, 'Cambria Math', 'Lucida Sans Unicode', 'Microsoft Sans Serif', 'Segoe UI Symbol', 'Arial Unicode MS', serif;\">3+<\/span>\u00a0ions have substituted for Y<span style=\"box-sizing: border-box; margin: 0px; padding: 0px; font-size: 13.5px; line-height: 0; position: relative; vertical-align: baseline; top: -0.5em; color: #2e2e2e; font-family: NexusSerif, Georgia, 'Times New Roman', Times, STIXGeneral, 'Cambria Math', 'Lucida Sans Unicode', 'Microsoft Sans Serif', 'Segoe UI Symbol', 'Arial Unicode MS', serif;\">3+<\/span>\u00a0ions in the lattice. The emission and excitation spectra of these phosphors show the characteristic photoluminescence spectra of Ce<span style=\"box-sizing: border-box; margin: 0px; padding: 0px; font-size: 13.5px; line-height: 0; position: relative; vertical-align: baseline; top: -0.5em; color: #2e2e2e; font-family: NexusSerif, Georgia, 'Times New Roman', Times, STIXGeneral, 'Cambria Math', 'Lucida Sans Unicode', 'Microsoft Sans Serif', 'Segoe UI Symbol', 'Arial Unicode MS', serif;\">3+<\/span>\u00a0ions. Based on the analyses of the diffuse reflection spectra and the PL spectra, a systematic energy diagram of Ce<span style=\"box-sizing: border-box; margin: 0px; padding: 0px; font-size: 13.5px; line-height: 0; position: relative; vertical-align: baseline; top: -0.5em; color: #2e2e2e; font-family: NexusSerif, Georgia, 'Times New Roman', Times, STIXGeneral, 'Cambria Math', 'Lucida Sans Unicode', 'Microsoft Sans Serif', 'Segoe UI Symbol', 'Arial Unicode MS', serif;\">3+<\/span>\u00a0ion in the forbidden band of sample with\u00a0<em style=\"box-sizing: border-box; margin: 0px; padding: 0px; color: #2e2e2e; font-family: NexusSerif, Georgia, 'Times New Roman', Times, STIXGeneral, 'Cambria Math', 'Lucida Sans Unicode', 'Microsoft Sans Serif', 'Segoe UI Symbol', 'Arial Unicode MS', serif; font-size: 18px;\">x<\/em>=0.02 is given. The best doping Ce content in these phosphors is \u223c2\u00a0mol%. The quenching temperature is \u223c405\u00a0K for the 2\u00a0mol% Ce content sample. The luminescence decay properties were investigated. The primary studies indicate that these phosphors are potential candidates for application in three-phosphor-converted white LEDs <a href=\"https:\/\/www.eastgonflable.fr\/e106064-taureau-mecanique.html\" style=\"color: grey; text-decoration: none;\">taureau machine<\/a>.<\/span><\/address>","protected":false},"excerpt":{"rendered":"<p>J. Lumin., 2011, 131, 2, 336. https:\/\/doi.org\/10.1016\/j [&hellip;]<\/p>\n","protected":false},"author":4,"featured_media":0,"comment_status":"closed","ping_status":"open","sticky":false,"template":"","format":"aside","meta":{"footnotes":""},"categories":[18],"tags":[35,62],"class_list":["post-79","post","type-post","status-publish","format-aside","hentry","category-lab_papers_2011","tag-ce3","tag-62","post_format-post-format-aside"],"_links":{"self":[{"href":"http:\/\/ustb.cc\/zh\/wp-json\/wp\/v2\/posts\/79","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/ustb.cc\/zh\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/ustb.cc\/zh\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/ustb.cc\/zh\/wp-json\/wp\/v2\/users\/4"}],"replies":[{"embeddable":true,"href":"http:\/\/ustb.cc\/zh\/wp-json\/wp\/v2\/comments?post=79"}],"version-history":[{"count":3,"href":"http:\/\/ustb.cc\/zh\/wp-json\/wp\/v2\/posts\/79\/revisions"}],"predecessor-version":[{"id":3180,"href":"http:\/\/ustb.cc\/zh\/wp-json\/wp\/v2\/posts\/79\/revisions\/3180"}],"wp:attachment":[{"href":"http:\/\/ustb.cc\/zh\/wp-json\/wp\/v2\/media?parent=79"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/ustb.cc\/zh\/wp-json\/wp\/v2\/categories?post=79"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/ustb.cc\/zh\/wp-json\/wp\/v2\/tags?post=79"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}