{"id":999,"date":"2021-09-16T21:38:59","date_gmt":"2021-09-16T13:38:59","guid":{"rendered":"http:\/\/polyhedra.cn\/zh\/?p=999"},"modified":"2023-09-10T19:49:08","modified_gmt":"2023-09-10T11:49:08","slug":"temperature-driven-n-p-conduction-type-switching-without-structural-transition-in-a-cu-rich-chalcogenide-nacu5s3","status":"publish","type":"post","link":"http:\/\/ustb.cc\/zh\/temperature-driven-n-p-conduction-type-switching-without-structural-transition-in-a-cu-rich-chalcogenide-nacu5s3\/","title":{"rendered":"Temperature-driven n\u2013p conduction type switching without structural transition in a Cu-rich chalcogenide, NaCu5S3"},"content":{"rendered":"\n<p class=\"has-black-color has-text-color\"><em><strong><br><\/strong><mark style=\"background-color:rgba(0, 0, 0, 0)\" class=\"has-inline-color has-vivid-cyan-blue-color\"><strong>Chem. Commun<\/strong><\/mark><strong>.<\/strong><\/em>, <strong>2020,56, 4882-4885<\/strong>. <a href=\"https:\/\/doi.org\/10.1039\/D0CC01429J\" data-type=\"URL\" data-id=\"https:\/\/doi.org\/10.1039\/D0CC01429J\">https:\/\/doi.org\/10.1039\/D0CC01429J<\/a><\/p>\n\n\n<div class=\"wp-block-image\">\n<figure class=\"aligncenter size-large\"><img decoding=\"async\" src=\"https:\/\/pubs.rsc.org\/en\/Image\/Get?imageInfo.ImageType=GA&amp;imageInfo.ImageIdentifier.ManuscriptID=D0CC01429J&amp;imageInfo.ImageIdentifier.Year=2020\" alt=\"\"\/><\/figure>\n<\/div>\n\n\n<p>We report for the first time the discovery of reversible n\u2013p conduction type switching in a chalcogenide, NaCu<small><sub>5<\/sub><\/small>S<small><sub>3<\/sub><\/small>, without structural transition. AC impedance and first-principles simulations of the ionic migration confirmed the local melting trends of the hexagonal copper lattice at high temperatures, which could result in superionic conductivity within NaCu<small><sub>5<\/sub><\/small>S<small><sub>3<\/sub><\/small>.<\/p>\n","protected":false},"excerpt":{"rendered":"<p>Chem. Commun., 2020,56, 4882-4885. https:\/\/doi.org\/10.1 [&hellip;]<\/p>\n","protected":false},"author":6,"featured_media":0,"comment_status":"open","ping_status":"open","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[27],"tags":[113],"class_list":["post-999","post","type-post","status-publish","format-standard","hentry","category-lab_papers_2020","tag-113"],"_links":{"self":[{"href":"http:\/\/ustb.cc\/zh\/wp-json\/wp\/v2\/posts\/999","targetHints":{"allow":["GET"]}}],"collection":[{"href":"http:\/\/ustb.cc\/zh\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/ustb.cc\/zh\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/ustb.cc\/zh\/wp-json\/wp\/v2\/users\/6"}],"replies":[{"embeddable":true,"href":"http:\/\/ustb.cc\/zh\/wp-json\/wp\/v2\/comments?post=999"}],"version-history":[{"count":5,"href":"http:\/\/ustb.cc\/zh\/wp-json\/wp\/v2\/posts\/999\/revisions"}],"predecessor-version":[{"id":2471,"href":"http:\/\/ustb.cc\/zh\/wp-json\/wp\/v2\/posts\/999\/revisions\/2471"}],"wp:attachment":[{"href":"http:\/\/ustb.cc\/zh\/wp-json\/wp\/v2\/media?parent=999"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/ustb.cc\/zh\/wp-json\/wp\/v2\/categories?post=999"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/ustb.cc\/zh\/wp-json\/wp\/v2\/tags?post=999"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}