Inorg. Chem., 2019, 58, 13, 8694–8701. https://pubs.acs.org/doi/abs/10.1021/acs.inorgchem.9b01020

The Sr₃SiO₅:Eu²⁺ phosphor has attracted considerable attention for applications in white LEDs owing to its highly efficient yellow emission under violet-blue excitation. We report herein an enhancement of yellow persistent luminescence in Sr₃SiO₅:Eu²⁺ through Ge incorporation. The strongest persistent luminescence intensity is observed for Sr₃(Si_1–xGe_x)O₅:Eu²⁺ with x = 0.005 with a peak emission wavelength at ∼580 nm and a persistent time of ∼7000 s at the 0.32 mcd/m² threshold value after UV radiation. A combination of thermoluminescence measurements and density functional theory (DFT) calculations reveals that the afterglow enhancement is due to a significant increase in the number of oxygen vacancies that act as electron trapping centers with appropriate trap depths. This investigation is anticipated to encourage more exploration of Ge_Si substitution to design and improve Si-containing persistent phosphors with superior functionalities.