Chem. Mater. 2019, 31, 9, 3333–3339. https://pubs.acs.org/doi/abs/10.1021/acs.chemmater.9b00410

Lead-free halide double perovskites continue to draw increasing attention in view of their nontoxicity and stability compared to lead-based perovskites. Herein, we optimized the colloidal synthesis of undoped and Bi-doped Cs₂AgInCl₆ nanocrystals (NCs) via the facile hot-injection process using nontoxic and available precursors. The synthesis conditions including temperature, ligands, and hydrochloric acid are investigated to boost the photoluminescence quantum yield (PLQY) of Cs₂AgInCl₆:Bi NCs with the trace amount of Bi doping. The broad-band orange emission peaking at 580 nm is observed with the PLQY as high as ∼11.4%, and the related luminescence mechanism has been discussed. This work provides a reliable avenue toward the optimization of optical properties for emerging lead-free halide perovskite NCs with enhanced PLQY.