J. Mater. Chem. C, 2020,8, 7322-7329. https://doi.org/10.1039/D0TC00562B

Organic–inorganic hybrid metal halides have received extensive attention owing to their versatile structures and optoelectronic properties. Herein, we report two lead-free metal halides, (PMA)₃BiBr₆ and (PMA)₃SbBr₆ [PMA⁺: (C₆H₅CH₂NH₃)⁺, as the abbreviation of phenylmethylammonium], which possess iso-structural zero-dimensional structures and crystallize in the monoclinic space group P2₁/c. (PMA)₃BiBr₆ and (PMA)₃SbBr₆ exhibit optical band gaps of ∼3.50 and 3.40 eV, respectively, and density functional theory calculations reveal their indirect bandgap behaviors. Upon 350 and 425 nm excitation, (PMA)₃BiBr₆ and (PMA)₃SbBr₆ exhibit broadband emission peaking at 510 nm and 625 nm with wide full-widths at half-maximum of ∼153 and 175 nm, respectively. The emission mechanism of the metal halides is attributed to self-trapped exciton emission. The relationship between the crystal structure and luminescence intensity is also discussed. Finally, both metal halides have high decomposition temperatures and are stable for long-term storage under ambient conditions, demonstrating their potential for optoelectronic applications.